You can only have one statement in the set argument blocks, otherwise you get the error shown. Erp.Tables.JobOper; is your first statement, the rest is the second. If you need more than one statement, you can set your variable in a custom code block instead.
Db.QuoteHed.Where( r =>r.Company == MyCompany && r.QuoteNum == QuoteToFind).Select( r =>r.MyUDField_c ).DefaultIfEmpty("Not Found").FirstOrDefault();
Obviously adjust for your table and conditions, and type. The .DefaultIfEmpty("Not Found") part is optional. Use it to return a specific value if no records matched the conditions.